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torsdag 6 mars 2014

Mystery of Planck's Constant h Uncovered


Planck introduced Planck's constant h in his proof of Planck's law using statistics based on an ad hoc assumption that the "smallest packet of energy" or "quantum of action" of a wave of (spatial) frequency \nu is equal to h\nu. Later h appeared in Schrödinger's wave equation as a measure of the diameter of an atom. Planck's constant thus has two meanings and the connection has remained a mystery, well supported by a statistical interpretation of the wave function as solution to the wave equation and with the photon as a mysterious particle of energy h\nu.

To seek to resolve the mystery let us consider the wave mechanics without reference to statistics presented in Mathematical Physics of Blackbody Radiation and Computational Blackbody Radiation, which offers a New View of blackbody radiation based on a generic wave model of a blackbody (as a web of vibrating atoms) with the following radiation spectrum of the principal form of Planck's law:
  • R_\nu (T) =\gamma T\nu^2 for \nu\le \frac{T}{h},
  • R_\nu (T) = 0 for \nu > \frac{T}{h},
where T is temperature, \nu is frequency and \gamma and h are two parameters with \nu > \frac{T}{h} representing a high-frequency cut-off. Radiative equilibrium between two such blackbodies defined by parameters with the same high frequency cut-off, shows that \gamma h=C where C is a universal constant. The generic wave model thus effectively depends on one parameter, which we take to be h as a representation of Planck's constant. We here assume that Boltzmann's constant k as a measure of energy per Kelvin is normalized to 1. 

We observe that the cut-off condition has the form
  • h\nu > T.
which gives the parameter h in the a wave model in computational form the meaning of a finite precision mesh parameter which can be connected to the diameter of the atoms forming the web supporting the wave model. We thus have only one meaning of Planck's constant h as a mesh size parameter.

In the New View based on wave mechanics there is no need to give h\nu a different meaning as a mysterious smallest "packet of energy or action" of a wave of frequency \nu and there is no need to speak about a particle named photon.  According to Ockham's razor this should be a step forward.

To view h as a measure of the size of atoms is rational and thus not mysterious. To view h\nu as a measure of "smallest packet of energy" of a wave of frequency \nu is irrational and thus mysterious.

Observing the radiation spectrum from a peephole of a cavity with graphite walls, as a physical wave model of a backbody, allows \gamma and h to be determined experimentally. This makes it possible to determine the size of atomistic microscopics in a macroscopic experiment.

From the standard non-normalized values h = 6.626\times 10^{-34} and k = 1.381\times 10^{-23}, we have with normalization to k=1 that h = 4.8\times 10^{-11} which is of atomistic size. With T = 480\, K we thus find a cut-off frequency of 10^{13} in the infrared visible range. 

2 kommentarer:

  1. Could you clarify what you mean with h=4.8*10^-11 being of atomistic scale?

    It looks like you are dividing h with k, but since they both have units you end up with

    h/k = 4.8*10^-11 Js/(J/K) = 4.8*10^-11 sK

    In what way is this on atomistic scale?

    SvaraRadera
  2. h/k has the dimension of T/f with f frequency connected to wave length as highest frequency which can be carried by a web of oscillating atoms at temp T.

    SvaraRadera