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onsdag 10 augusti 2016

New Quantum Mechanics 14: H^- Ion

Below are results for the H^- ion with two electrons and a proton. The ground state energy comes out as -0.514, slightly below the energy -0.5 of H, which means that H is slightly electro-negative and thus by acquiring an electron into H^- may react with H^+ to form H2 (with ground state energy -1.17), as one possible route to formation of H2. Another route is covered in this post with two H atoms being attracted to form a covalent bond.

The two electron wave functions of H^- occupy half-spherical domains (depicted in red and blue) and meet at a plane with a homogeneous Neumann condition satisfied on both sides.

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