Thermodynamics of Friction

Everything goes around in construction-deconstruction-construction...

In the previous post we considered viscosity in laminar and turbulent flow and friction between solid bodies as mechanisms for irreversible transformation of large scale kinetic motion/energy into small scale kinetic motion/energy in the form of heat energy, noting that the transformation cannot be reversed since the required very high precision cannot be realised, everything captured in a 2nd Law of Thermodynamics.  

Let us consider the generation of heat energy in friction when rubbing your hands or sliding an object over a floor or pulling the handbrakes of your bicycle. We understand that the heat energy is created from the work done by force times displacement (in the direction of the force), like pressing/pushing a sandpaper over the surface of a piece of wood to smoothen the surface by destroying its granular micro-structure. Work is thus done to destroy more or less ordered micro-structure and the work shows up as internal heat energy as unordered micro-scale kinetic energy. 

The key is here destruction of micro-structure into heat energy in a process which cannot be reversed since the required precision cannot me met.

Skin friction between a fluid and solid acts like friction between solids. 

Turbulent flow transforms large scale ordered kinetic energy into small-scale unordered kinetic energy as heat energy under the action of viscous forces. Laminar flow also generates heat energy from friction between layers of fluid of different velocity.

In all these cases heat energy is generated from destruction/mixing of order/structure in exothermic irreversible processes. This destruction is balanced by constructive processes like synchronisation of atomic oscillations into radiation and emergence of ordered structures like vortices in fluid flow and endothermic processes of unmixing/separation. 

We thus see exothermic processes of destruction followed by endothermic construction, which is not reversed deconstruction, with different time scales where deconstruction is fast and brutal without precision and construction is slow with precision. This is elaborated in The Clock and the Arrow in popular form. Take a look.

 

How to Generate Heat Energy

We recall from a previous post:

• Heat energy can be generated from large scale kinetic energy by compression. 
• Kinetic energy can be generated from heat energy by expansion.

More precisely, we saw in the previous saw that heat energy at high temperature can generate useful mechanical work. Heat energy at high temperature can be created by nuclear/chemical reactions. 

Heat energy typically at lower temperatures also appears as losses from electrical currents subject to resistance, fluid motion subject to turbulent/laminar viscosity and friction between solid bodies. These losses appear as substantial, unavoidable and irreversible as expressions of a 2nd Law.

We have seen that heat energy $\sim T\nu^2$ of frequency $\nu$ carried by an atomic lattice of temperature $T$ subject to high-frequency cut-off $\nu <\frac{T}{h}$ expressing ordered synchronised atomic oscillation or kinetic motion, can be radiated. Here $h$ is a constant. 

We can view turbulent dissipation in fluid flow as a form of high-frequency forcing above present cut-off which cannot be reradiated and so is absorbed as internal energy in the form of unordered small scale kinetic energy. We can similarly view viscosity and friction as forms of high-frequency forcing supplying internal energy. 

The contribution to internal energy increases the temperature and so allows unordered small scale motion to be synchronised to higher frequency and then radiated.  

The key is thus that turbulent, viscous and frictional dissipation all represent high-frequency forcing above   present cut-off, which cannot be represented and reradiated and so shows up as internal energy as small scale kinetic energy. 

Rubbing hands is one way to transform large scale kinetic motion into small scale kinetic motion as heat energy. The brakes on your car work the same way.