Difference Between Emission and Absorption of Radiation

In a sequence of posts on radiative heat transfer and DLR/backradiation I have studied a wave model of the form:

• $U_{tt} - U_{xx} - \gamma U_{ttt} - \delta^2U_{xxt} = f $

where the subindices indicate differentiation with respect to space $x$ and time $t$, and

1. $U_{tt} - U_{xx}$ represents a vibrating string with U displacement
2. $- \gamma U_{ttt}$ is a dissipative term modeling outgoing radiation = emission
3. $- \delta^2U_{xxt}$ is a dissipative modeling internal heating = absorption
4. $f$ is incoming forcing/microwaves,

where $\gamma$ and $\delta^2$ are positive constants connected to dissipative losses as outgoing radiation = emission and internal heating = absorption.

We see emission represented by $-\gamma U_{ttt}$ and absorption by $-\delta^2U_{xxt}$. We now ask:

1. How is the distinction between emission and absorption expressed in this model?
2. Is Helmholtz Reciprocity valid (emission and absorption are reverse processes)?
3. Is Kirchhoff's Radiation Law (emissivity = absorptivity) valid?

Before seeking answers let us recall the basic energy balance between incoming forcing $f$ measured as

• $F = \int f^2(x,t)\, dxdt$

assuming periodicity in space and time and integrating over periods, and (rate of) outgoing radiation = emission $R$ measured by

• $R = \int \gamma U_{tt}^2\, dxdt$,

the oscillator energy $OE$ measured by

• $OE =\frac{1}{2}\int (U_t^2 + U_x^2)\, dxdt$

and (rate of) internal energy = absorption measured by

• $IE = \int \delta^2U_{xt}^2\, dxdt$

with the energy balance in stationary state expressed as

• $F = R + IE$
• incoming energy = emission + absorption.

The model has a frequency switch switching from emission to absorption as the frequency increases beyond a certain threshold proportional to temperature in accordance with Wien's displacement law.

We now return to questions 1 - 3.

Both terms generate dissipative effects when multiplied with $U_t$ as $R = \int \gamma U_{tt}^2\, dxdt$ and $IE = \int \delta^2U_{xt}^2\, dxdt$, but the terms involve different derivatives with $U_{tt}$ acting only in time and $U_{xt}$ acting also in space.

The absorption $U_{xt}^2$ represents a smoothing effect in space, which is irreversible and thus cannot be reversed into emission as reversed absorption.

The emission $U_{tt}^2$ represents a smoothing effect in time, which is irreversible and thus cannot be reversed into absorption as reversed emission.

In other words, in the model both absorption and emission are time irreversible and thus cannot be reversed into each other.

We conclude that the model does not satisfy Helmholtz reciprocity.

Nevertheless, the model satisfies Kirchhoff's law as shown in a previous post.

Conclusion:

The space derivative in $U_{xt}$ models absorption as process of smoothing in space with irreversible transformation of high frequencies in space into low frequencies with a corresponding increase of internal energy as heat energy.

Absorbed high frequencies can with increasing temperature be rebuilt through (resonance in) the wave equation into high frequency emission.

Absorption and emission are not reverse processes, but my be transformed into each other

through (resonance in) the wave equation and the switch.

We may compare absorption with a catabolic process of destroying (space-time) structure and emission with an anabolic process of building structure, with the wave equation as a transformer.

For more details see Mathematical Physics of Blackbody Radiation and The Clock and the Arrow.

Helmholtz Reciprocity and DLR/Backradiation

Helmholtz Reciprocity Principle (HRP) states that absorption and emission of light can be viewed as reversed processes arising by reversal of time. Absorption of a light ray by a (black) body is simply emission of a light ray running backwards in time, or the other way around.

Downwelling Longwave Radiation (DLR) and backradiation seek justification by HRP. Kirchhoff's Radiation Law stating that emissivity and absorptivity of a radiating body are equal,

was justified by Planck with reference to HRP.

But is HRP a valid physical principle? What is the relation between HRP and the 2nd Law?

HRP describes reversible physics while the 2nd Law described irreversible physics, and so HRP and the 2nd Law describe different physics.

Is the real physics of absorption and emission the time reversal of each other? Probably not.

The process of absorption is like reading and the process of emission like writing. To state

that reading and writing are the reverse of each other would miss the difference between the active constructive aspect of reading and the passive consumption aspect of reading.

The analysis in Mathematical Physics of Blackbody Radiation shows that absorption and emission are different processes satisfying a 2nd law which does not allow time reversal, and thus indicates that HRP is not valid.

Without HRP the support of DLR/backradiation evaporates.

Note that HRP conforms to a corpuscular theory of light as photon particles for which time reversal is no problem. But such a theory is capable of describing only simple ray tracing physics and not real physics.