We see that the transmittance is zero in the narrow interval 664 - 668, where 400 ppm CO2 makes the atmosphere opaque, while outside this interval the transmittance is low only in a small portion of the spectrum. In other words, the total emissivity of 400 ppm CO2 is very small which means that CO2 has a very limited capability to "block radiation" from the Earth surface, thus contradicting typical OLR spectra with full blocking in the interval 600 - 800.
Further, changing to 600 ppm gives almost the same transmittance spectrum, signaling small radiative forcing from doubling of the preindustrial concentration of CO2:
PS Further evidence is given by Ed Caryl.
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