lördag 18 oktober 2025

Quantum Restart 2026 from Hydrogen Atom 1926

This year has been designated as the International Year of Quantum Science and Technology (IYQ2025) by the United Nations as the 100th anniversary of the development of Quantum Mechanics. 

Quantum Mechanics was kick-started fin 1926 with formulation Schrödinger's Equation SE for the Hydrogen atom with one electron,  followed by a swift generalisation to many electrons by Born-Heisenberg-Dirac to form the text book Copenhagen Interpretation CI of Standard QM of today.

StdQM is generally viewed as a formidable success underlying all of modern technology of microscopics, but none of the foundational problems behind the CI have been resolved. StdQM is viewed to "always work perfectly well" but "nobody understands why". 

The previous post recalled the critical moment in 1926 when SE was generalised to many electrons by Born-Heisenberg-Dirac into StdQM under heavy protests from Schrödinger, who took the first step with a SE in a wave function $\Psi (x)$ depending on a 3d space coordinated $x$ with $\rho (x)=\Psi^2 (x)$ representing charge density in a classical sense. 

Recall that RealQM is a generalisation to many electrons different from StdQM by staying within a framework of classical continuum mechanics in the spirit of Schrödinger. The basic assumption is that an atom with $N$ electrons is represented by a nucleus surrounded by a collection of electrons as    

  • non-overlapping unit charge densities $\rho_i(x)$ for $i=1,....,N$, 
  • free of self-interaction,
  • indivisible in space. 
Let us now compare RealQM and StdQM in the case of Hydrogen. For stationary ground states and excited states so called eigenstates, they share formally the same SE but with different interpretations of the wave function:

  1. $\rho (x)$ is charge density in classical sense. (RealQM)
  2. $\rho (x)$ is probability density in StdQM sense. (StdQM) 

Recall that QM was formed from a perceived difficulty of capturing the spectrum of Hydrogen within classical physics with the spectrum arising from interaction of the atom with an exterior forcing electromagnetic field in so called stimulated radiation. 

Schrödinger resolved this problem by extending SE to a time-dependent form where the frequencies of the spectrum appeared as differences of stationary energy levels, thus with a linear relation between atomic energy levels and resonance frequencies in stimulated radiation. The discrete frequencies appeared as 

  • beat frequencies of wave functions in superposition. 
This became the mantra of StdQM which has ruled for 100 years, with superposition signifying the break with classical physics, where superposition in spatial sense is impossible.

If we stay within RealQM, then superposition is impossible because charge densities do not overlap. We now ask the key question:
  • Is it possible to capture the spectrum of Hydrogen within RealQM thus without superposition? 
The discrete stationary eigenstates are the same, and so we ask about the time-dependent form of RealQM? Is it the same as that of StdQM? Not in general because RealQM is non-linear and StdQM linear. For Hydrogen RealQM is linear so in this case the same time-dependence as in StdQM is possible.

But this may not be most natural from a classical point of view without superposition in mind. Instead it is natural to think of the radiating electron oscillating back and forth between two energy levels with different charge densities as a classical oscillating dipole. We can thus extend RealQM to a classical dynamical system swinging back and forth between energy levels with different charge distributions. This would describe the radiating Hydrogen atom in terms of classical physics with a continuous transition between different configurations. This would answer Schrödinger's basic question without answer in STdQM about "electron jumps": The electron does not jump but changes charge density continuously in space and time. 

The only thing to explain in this scenario is the linear relation between (difference of) energy and frequency, not from beat frequency and superposition, but from the basic relation between energy and frequency appearing in Planck's Law discussed in this post. 

Summary: It seems possible to capture atomic radiation by RealQM within a classical continuum mechanics framework and so avoid taking the step out of classical physics along the dream of Schrödinger. In particular, superposition is not required and probably not present. Quantum computers built on superposition will not work. Superposition may be superstition rather than reality.  

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