This year has been designated as the International Year of Quantum Science and Technology (IYQ2025) by the United Nations as the 100th anniversary of the development of Quantum Mechanics.
Quantum Mechanics was kick-started fin 1926 with formulation Schrödinger's Equation SE for the Hydrogen atom with one electron, followed by a swift generalisation to many electrons by Born-Heisenberg-Dirac to form the text book Copenhagen Interpretation CI of Standard QM of today.
StdQM is generally viewed as a formidable success underlying all of modern technology of microscopics, but none of the foundational problems behind the CI have been resolved. StdQM is viewed to "always work perfectly well" but "nobody understands why".
The previous post recalled the critical moment in 1926 when SE was generalised to many electrons by Born-Heisenberg-Dirac into StdQM under heavy protests from Schrödinger, who took the first step with a SE in a wave function $\Psi (x)$ depending on a 3d space coordinated $x$ with $\rho (x)=\Psi^2 (x)$ representing charge density in a classical sense.
Recall that RealQM is a generalisation to many electrons different from StdQM by staying within a framework of classical continuum mechanics in the spirit of Schrödinger. The basic assumption is that an atom with $N$ electrons is represented by a nucleus surrounded by a collection of electrons as
- non-overlapping unit charge densities $\rho_i(x)$ for $i=1,....,N$,
- free of self-interaction,
- indivisible in space.
- $\rho (x)$ is charge density in classical sense. (RealQM)
- $\rho (x)$ is probability density in StdQM sense. (StdQM)
Recall that QM was formed from a perceived difficulty of capturing the spectrum of Hydrogen within classical physics with the spectrum arising from interaction of the atom with an exterior forcing electromagnetic field in so called stimulated radiation.
Schrödinger resolved this problem by extending SE to a time-dependent form where the frequencies of the spectrum appeared as differences of stationary energy levels, thus with a linear relation between atomic energy levels and resonance frequencies in stimulated radiation. The discrete frequencies appeared as
- beat frequencies of wave functions in superposition.
- Is it possible to capture the spectrum of Hydrogen within RealQM thus without superposition?
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