- $\ddot u (t) +\omega^2u(t) -\gamma\dddot u = f(t)\approx \sin(\omega t)$,
The dynamics of near-resonance is quite subtle as explained in detail on Computational Blackbody Radiation showing that Planck's constant enters as a parameter in a high-frequency cut-off reflecting Wien's displacement law.
Atomic emission can be described as an eigenvalue problem for Schrödinger's equation of the form
- $ih\dot\psi = E\psi$,
where $E$ is a real eigenvalue of an atomic Hamiltonian, with solution
- $\psi (t) =\exp(i\omega t) =\cos(\omega t)+i\sin(\omega t)$,
We conclude:
- Blackbody radiation is a near-resonance phenomenon of molecules or collections of atoms modeled as a forced harmonic oscillator with small damping. Collections of atoms vibrate without electron configurations changing energy.
- Atomic radiation is a direct resonance phenomenon which can be modeled by a harmonic oscillator. Electrons oscillate between two energy levels representing eigenstates of an atom.
In both cases $h$ enters combined with frequency $\nu$ in the form $h\nu =\bar h\omega$ as quantity of energy serving in a threshold condition in blackbody radiation, and as an energy eigenvalue in atomic emission.
The value of $h$ as setting a conversion scale between light energy and electronic energy can be determined by the photoelectric effect and can then be used by definition in blackbody radiation and Schrödinger's equation.
The value of $h$ as setting a conversion scale between light energy and electronic energy can be determined by the photoelectric effect and can then be used by definition in blackbody radiation and Schrödinger's equation.
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