måndag 3 november 2025

Hydrogen Spectrum as Classical Physics

This is a continuation of the previous post on the necessity to give up classical physics for quantum physics in its text book form of Standard Quantum Mechanics StdQM. We ask to what extent RealQM as a form of classical physics can explain the observed spectrum of the Hydrogen atom as expressed in stimulated radiation. We thus will compare

  • StdQM: Spectral line appears from superposition of wave functions of eigenstates. 
  • RealQM: Spectral line appears from oscillation between charge distributions of eigenstates.
In both cases the frequency of the spectral line scales with the difference of energy between eigenstates, but with different explanations: 
  • StdQM: Spectral frequency appears as beat frequency of wave functions with eigenfrequency variation in time according to the Schrödinger's equation. Connection between frequency and energy is secondary. Radiation can appear to be spontaneous.
  • RealQM: Spectral frequency is not beat frequency, but simply the frequency $\nu=\frac{\Delta E}{h}$ which matches the energy difference $\Delta E$ between eigenstates with $h$ Planck's constant in an assumed coupling between frequency and energy. There is an active exchange of energy between atom and radiation field with frequency matching the jump in energy. The atom is forced to respond to radiation of certain frequency as a dipole. The radiation is not spontaneous. 
We see that StdQM offers an explanation in terms of time-dependent quantum mechanics without realism, while RealQM relies on the formal coupling between matter and radiation expressed by $E=h\nu$ appearing in blackbody radiation. Compare with this post on the physical meaning of $E=h\nu$.

We see that, at least in the case of stimulated radiation, the spectrum of an atom can be given a RealQM semi-classical explanation. It is not clear that StdQM offers something more enlightening. Or?

This discussion connects to quantum computing discussed in recent posts with StdQM supposed to support delicate superposition of wave functions free of forcing performing complex analog computations, while RealQM brings forward the aspect of forcing in terms of classical physics. 

PS Here is a chatGPT comment.

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