Planck's constant $h$ appears in several different contexts in quantum physics including
- Planck's Law of blackbody radiation.
- Schrödinger's Equation SE describing the spectrum of the Hydrogen atom.
Here 1. involves collective behaviour of atoms, while 2. concerns one atom. The standard view is that the double appearance of $h$ in two fundamentally different contexts is an expression of a deep connection in a mysterious quantum world, which cannot be understood.
Let us see if we can uncover some the mystery. We recall from this post that $h$ was introduced by Planck in 1900 to make Planck's Law fit with observation, specifically in a high frequency cut-off factor $C(\alpha )$ with $\alpha =\frac{h\nu}{kT}$ where $\nu$ is frequency, and $k$ as Boltzmann's constant combined with temperature $T$ into $kT$ serves as an energy per degree of freedom in thermodynamics. For $h\nu << kT$ then $C(\alpha ) =1$ and for $h\nu >kT$, $C(\alpha )$ decays to zero. The quantity $h\nu$ is thus compared to the elementary energy $kT$ and so $h\nu$ is referred to as a basic quantum of energy $E=h\nu$ connected to the frequency $\nu$. This is a linear relation and $h$ is the constant of proportionality between energy and frequency.
Energy $E$ is thus connected to frequency $\nu$ by $E=h\nu$ with physical meaning of setting the high-frequency cut-off in Planck's Law in relation to $kT$. This explains the function of $h$ in 1. as serving in high frequency cut-off. High-frequency connects to small-wavelength which connects to spatial resolution. Wien's displacement law takes the form $\nu \approx \frac{k}{h}T$ with linear scaling between frequency and temperature as measure of energy. We see that $h$ appears in a high-frequency threshold condition scaling with $T$ which gives $h$ a physical meaning but not as measure of physical quantity representing some smallest quantum of energy $h\nu$. Threshold condition and not physical quantity.
We now turn to 2. recalling Schrödinger's Equation SE with $H$ a Hamiltonian:
- $ih\frac{\partial\psi}{\partial t}+H\psi =0$
- The value of $h$ as conversion factor between energy and frequency as $E=h\nu$ in a linear relation, is set to make Planck's Law fit with observation.
- That value of $h$ is then inserted by design into SE to keep the $E=h\nu$ linear relation between energy and frequency.
- The design is elaborated by connecting a one electron energy jump $E$ to emission/absorption of one photon of frequency $\nu$ determined by $\nu =\frac{E}{h}$ as the mechanism behind the spectrum of Hydrogen.
- In short: The appearance of $h$ is SE is not deep mystery, but simply the design of SE.
- Is the fact that SE describes the observed spectrum of Hydrogen a mystery? Not with charge density representation of the wave function solution to SE, in which case SE has classical continuum mechanical form of a vibrating elastic body and as such not a mystery.
- Extension to atoms with more than one electron presents new questions to be answered differently by Standard QM and RealQM.
Inga kommentarer:
Skicka en kommentar