Here is a reflection connecting to the previous post on RealQM as a computable model of atoms and molecules and Mearmin's Shut up and Calculate desperate reaction to the difficulty of making sense of the theory of Standard Quantum Mechanics StdQM.
Let us recall the following views on the divide between StdQM as the theoretical foundation of chemistry according to physicists and the theoretical chemistry actually used by chemists.
Eberhardt 2012:
- Chemistry is a discipline of two faces, one applied and the other theoretical. The applied face focuses on the design and synthesis of molecules and solids, while the theoretical face looks for explanations of a molecule or solid’s properties.
Bader 2011:
- ....the divide that exists in chemistry between those who seek their understanding within a universe wherein the laws of physics apply and those who prefer alternative universes wherein the laws are suspended or bent to suit preconceived ideas.
Dirac 1929:
- The underlying physical laws necessary for the mathematical theory of a large part of physics and the whole of chemistry are thus completely known and the difficulty is only that the exact application of these laws leads to equations much too complicated to be soluble. It therefore becomes desirable that approximate practical methods of applying quantum mechanics should be developed, which can lead to an explanation of the main features of complex atomic systems without too much computation.
Dirac identifies the root cause of the divide as the impossibility of solving Schrödinger's equation of StdQM for the complex atomic systems of chemistry. If computational solution was possible there would be no divide and the whole of chemistry would be like an open book to read by computation.
RealQM is an alternative to StdQM which is ab initio computable for the complex atomic systems of chemistry and is also understandable in the same sense as classical continuum mechanics. If RealQM indeed shows to models physics, then there is no longer any reason for a divide between theory and practice. The Shut up and Calculate can then be replaced by Compute, Learn and Speak.
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